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Measurement of dynamic fracture toughness and failure behavior for explosive mock materials

Pengwan CHEN, Zhongbin ZHOU, Shaopeng MA, Qinwei MA, Fenglei HUANG

《机械工程前沿（英文）》 2011年第6卷第3期页码 292-295 doi: 10.1007/s11465-011-0237-8

摘要：

In this work, a pre-cracked semi-circular shaped explosive simulant was loaded using a split Hopkinson pressure bar (SHPB). A high-speed camera was used to capture the deformation and fracture process of the specimen in situ. The digital images were processed using the digital image correlation (DIC) method. Next, full displacement and strain fields were obtained. The displacement vector field shows that the specimen fractured under tensile stress action. The strain field can be used to predict the crack propagation. Results show that the method of combined DIC and SHPB is effective to study the dynamic deformation and fracture behavior of explosive simulants. In addition, the specimen was loaded using a drop weight. The fracture toughness of the specimen was preliminary measured.

关键词： digital image correlation polymer bonded explosive simulant split Hopkinson pressure bar (SHPB) semicircular bending test deformation fracture toughness

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Printability and hardening performance of three-dimensionally-printed geopolymer based on lunar regolith simulant

《结构与土木工程前沿（英文）》 doi: 10.1007/s11709-023-0003-0

摘要： Using an in situ lunar regolith as a construction material in combination with 3D printing not only reduces the weight of materials carried from the Earth but also improves the automation of lunar infrastructure construction. This study aims to improve the printability of a geopolymer based on a BH-1 lunar regolith simulant, including the extrudability, open time, and buildability, by controlling the temperature and adding admixtures. Rheological parameters were used to represent printability with different water-to-binder ratios, printing temperatures, and contents of additives. The mechanical properties of the hardening geopolymer with different filling paths and loading directions were tested. The results show that heating the printed filaments with a water-to-binder ratio of 0.32 at 80 °C can adjust the printability without adding any additive, which can reduce the construction cost of lunar infrastructure. The printability of the BH-1 geopolymer can also be improved by adding 0.3% Attagel-50 and 0.5% polypropylene fiber by mass at a temperature of 20 °C to cope with the changeable environmental conditions on the Moon. After curing under a simulated lunar environment, the 72-h flexural and compressive strengths of the geopolymer specimens reach 4.1 and 48.1 MPa, respectively, which are promising considering that the acceleration of gravity on the Moon is 1/6 of that on the Earth.

关键词： geopolymer lunar regolith simulant 3D printing rheology printability

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模拟深水环境爆炸容器动力响应实验研究

钟冬望,李琳娜

《中国工程科学》 2014年第16卷第11期页码 78-81

摘要：

对可模拟200 m水深、10 g TNT当量的爆炸容器在不同加载静压和内部爆炸载荷下的动力响应进行了实验研究，通过监测容器6 个特征点的动态应变波形，分析了容器壳体的振动特性和动力学强度。测试结果揭示了在加载静压和内部爆炸载荷条件下容器的动态响应规律，为模拟深水环境爆炸容器的设计研制提供了参考。

关键词：深水爆炸爆炸容器动力响应应变

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bond enhancement using carbon nanotubes on flexural behavior of RC beams strengthened with externally bonded

《结构与土木工程前沿（英文）》 2022年第16卷第1期页码 131-143 doi: 10.1007/s11709-021-0787-8

摘要： This paper studied the effect of incorporation of carbon nanotubes (CNTs) in carbon fiber reinforced polymer (CFRP) on strengthening of reinforced concrete (RC) beams. The RC beams were prepared, strengthened in flexure by externally bonded CFRP or CNTs-modified CFRP sheets, and tested under four-point loading. The experimental results showed the ability of the CNTs to delay the initiation of the cracks and to enhance the flexural capacity of the beams strengthened with CFRP. A nonlinear finite element (FE) model was built, validated, and used to study the effect of various parameters on the strengthening efficiency of CNTs-modified CFRP. The studied parameters included concrete strength, flexural reinforcement ratio, and CFRP sheet configuration. The numerical results showed that utilization of CNTs in CFRP production improved the flexural capacity of the strengthened beams for U-shape and underside-strip configurations. The enhancement was more pronounced in the case of U-shape than in the case of use of sheet strip covers on the underside of the beam. In case of using underside-strip, the longer or the wider the sheet, the higher was the flexural capacity of the beams. The flexural enhancement of RC beams by strengthening with CNTs-modified CFRP decreased with increasing the rebar diameter and was not affected by concrete strength.

关键词： RC beams flexural strengthening CFRP CNTs finite element

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反爆炸恐怖袭击防排爆技术综述

方向,高振儒,周守强,郭涛

《中国工程科学》 2013年第15卷第5期页码 80-83

摘要：

爆炸袭击是最残酷、最血腥、最难防范的恐怖活动，防排爆是反爆炸恐怖袭击最直接的技术手段，其中涉及搜爆、排爆、防爆等技术装备和方法。近年来，反爆炸恐怖袭击防排爆技术取得了很大进步，但还存在许多技术难题。本文主要分析了爆炸恐怖活动规律、搜排爆装备技术和防护技术现状，研究了爆炸物探测和防排爆的技术途径，针对现有装备技术的局限性提出了研究的方向和思路。

关键词：爆炸恐怖搜爆排爆防爆

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Optimization of polyurethane-bonded thin overlay mixture designation for airport pavement

Xianrui LI; Ling XU; Qidi ZONG; Fu JIANG; Xinyao YU; Jun WANG; Feipeng XIAO

《结构与土木工程前沿（英文）》 2022年第16卷第8期页码 947-961 doi: 10.1007/s11709-022-0836-y

摘要： This research explored the application potential of PUM thin-overlay technology on airport rapid maintenance. The rapid curing process of polyurethane binder determines the limited time window for mixing and construction of polyurethane-bonded mixture (PUM), which presents significant difference with hot-mix asphalt (HMA) technology. Therefore, this research investigated and optimized the mix design of PUM for airport thin-overlay technology based on its thermosetting characteristics. First, limestone and basalt were comprehensively compared as an aggregate for PUM. Then, the effects of molding and curing conditions were studied in terms of mixing time, molding method, molding parameters and curing temperature. Statistical analysis was also conducted to evaluate the effects of gradation and particle size on PUM performances based on gray relational analysis (GRA), thus determining the key particle size to control PUM performances. Finally, the internal structural details of PUM were captured by X-ray CT scan test. The results demonstrated that it only took 12 hours to reach 75% of maximum strength at a curing temperature of 50 °C, indicating an efficient curing process and in turn allowing short traffic delay. The internal structural details of PUM presented distribution of tiny pores with few connective voids, guaranteeing waterproof property and high strength.

关键词： polyurethane-bonded mixture mix design optimization airport pavement thin overlay gray relational analysis

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Anisotropy of multi-layered structure with sliding and bonded interlayer conditions

Lingyun YOU, Kezhen YAN, Jianhong MAN, Nengyuan LIU

《结构与土木工程前沿（英文）》 2020年第14卷第3期页码 632-645 doi: 10.1007/s11709-020-0617-4

摘要： A better understanding of the mechanical behavior of the multi-layered structure under external loading is the most important item for the structural design and the risk assessment. The objective of this study are to propose and develop an analytical solution for the mechanical behaviors of multi-layered structure generated by axisymmetric loading, and to investigate the impact of anisotropic layers and interlayer conditions on the multi-layered structure. To reach these objectives, first, according to the governing equations, the analytical solution for a single layer was formulated by adopting the spatial Hankel transform. Then the global matrix technique is applied to achieve the analytical solution of multi-layered structure in Hankel domain. The sliding and bonded interlayer conditions were considered in this process. Finally, the numerical inversion of integral transform was used to solve the components of displacement and stress in real domain. Gauss-Legendre quadrature is a key scheme in the numerical inversion process. Moreover, following by the verification of the proposed analytical solution, one typical three-layered flexible pavement was applied as the computing carrier of numerical analysis for the multi-layered structure. The results have shown that the anisotropic layers and the interlayer conditions significantly affect the mechanical behaviors of the proposed structure.

关键词： multi-layered structure Hankel transformation anisotropic transversely isotropic interlayer condition Gauss-Legendre quadrature

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Synthesis of mid-dicarboxy polystyrene by ATRP and formation of ionic-bonded supramolecules

YU Tao, WANG Yun, LU Dairen, BAI Ruke, LU Weiqi

《化学科学与工程前沿（英文）》 2007年第1卷第2期页码 140-145 doi: 10.1007/s11705-007-0026-4

摘要： Dimethyl 4, 6-bis (bromomethyl) isophthalate was synthesized by bromomethylation, oxidation, esterification and bromination of 1, 3-dimethylbenzene. This was used to initiate the atom transfer radical polymerization of styrene successfully. Results showed that the process had some of the good characteristics of controlled/living free radical polymerization. The molecular weight of the obtained polymer increased linearly with monomer conversion, its molecular weight distribution was very narrow, and a linear relationship between ln([]/[]) and polymerization time was found. A well-defined novel structural polystyrene containing two ester groups in the mid-main chain was prepared with controlled molecular weight and narrow polydispersity. The structure of the polymer was confirmed by H-NMR spectra. After being hydrolyzed, dicarboxy polystyrene was obtained and used to form ionic-bonded supramolecules with 1-dodecanamine as a model of the star-shaped supramolecules. The supramolecules formed were characterized by Fourier transform infrared (FTIR) spectrum.

关键词： controlled molecular conversion bromination relationship isophthalate

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Laser ablation of block copolymers with hydrogen-bonded azobenzene derivatives

Jintang Huang, Youju Huang, Si Wu

《化学科学与工程前沿（英文）》 2018年第12卷第3期页码 450-456 doi: 10.1007/s11705-018-1735-6

摘要：

Supramolecular assemblies (PS-b-P4VP(AzoR)) are fabricated by hydrogen-bonding azobenzene derivatives (AzoR) to poly(4-vinyl pyridine) blocks of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP). PS-b-P4VP(AzoR) forms phase separated nanostructures with a period of ~75–105 nm. A second length scale structure with a period of 2 µm is fabricated on phase separated PS-b-P4VP(AzoR) by laser interference ablation. Both the concentration and the substituent of AzoR in PS-b-P4VP(AzoR) affect the laser ablation process. The laser ablation threshold of PS-b-P4VP(AzoR) decreases as the concentration of AzoR increases. In PS-b-P4VP(AzoR) with different substituents (R= CN, H, and CH₃), ablation thresholds follow the trend: PS-b-P4VP(AzoCN)<PS-b-P4VP(AzoCH₃)<PS-b-P4VP(AzoH). This result indicates that the electron donor group (CH₃) and the electron acceptor group (CN) can lower the ablation threshold of PS-b-P4VP(AzoR).

关键词： laser ablation block copolymers hydrogen-bond azobenzene derivatives supramolecular assembly

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爆破器材与工程爆破新进展

汪旭光

《中国工程科学》 2002年第4卷第4期页码 36-40

摘要：

简要叙述了近5年来国内外爆破器材和工程爆破新进展，指出了未来的发展前景。

关键词：炸药起爆器材爆破

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基于BH-1模拟月壤的低碱高强地聚合物的制备与表征 Article

周思齐, 鲁乘鸿, 朱兴一, 李峰

《工程（英文）》 2021年第7卷第11期页码 1631-1645 doi: 10.1016/j.eng.2020.10.016

摘要：

建设月球基地以支持月面科研任务和资源利用一直是各国研究人员的目标。使用月球材料进行原位资源利用制备建筑材料对于节省昂贵的太空运费具有重要意义。本文研制了一种新型模拟月壤，名为北航（BH）-1。通过X射线荧光光谱（XRF）、X射线衍射（XRD）、扫描电子显微镜（SEM）和反射光谱结果证实，BH-1 的化学矿物组成和微观结构与真实月壤非常相似。本研究还在模拟月球环境条件下合成了一种基于BH-1 模拟月壤的地聚合物，并研究了补充铝源对地聚合物强度的影响。测定了碱激发BH-1 浆体的流变性能。采用XRF、XRD、傅里叶红外光谱、SEM能谱分析和27Al 魔角旋转核磁共振分析对地聚合物进行表征。试验结果表明，BH-1 浆体的流变曲线符合Herschel-Bulkley 模型，表现为剪切变稀流体。添加铝源的BH-1 地聚合物与对照组相比，28 天抗压强度可提高100.8%。同时，产生单位强度所需的添加剂的质量降低，显著减少了从地球运输至月球用于地聚合物制备的材料质量，有望节约太空运输成本。微观实验分析表明，通过添加额外的铝源来改善BH-1 地聚合物的力学性能机理为：促进了硅氧基中铝原子基团对硅原子基团的取代作用，生成更致密的无定形凝胶结构。

关键词：深空探测月球基地地聚合物模拟月壤流变学

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柔性材料对爆炸载荷的缓冲效应研究

于少娟,李永池,刘颢文,孙宇新,胡秀章

《中国工程科学》 2007年第9卷第4期页码 75-78

摘要：

建立了柔性材料桙钢复合壳体在爆炸载荷作用下应力波传播问题的完备方程组；使用有限元方法完成了对复合壳体在爆炸载荷作用下应力波传播规律的系列数值模拟，并着重讨论了不同炸药层和柔性材料层厚度对柔性材料与钢交界面载荷的影响。

关键词：柔性材料爆炸载荷载荷改造数值模拟

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Organic conjugated polymers and polymer dots as photocatalysts for hydrogen production

《能源前沿（英文）》 2021年第15卷第1期页码 667-677 doi: 10.1007/s11708-021-0767-7

摘要： Owing to the outstanding characteristics of tailorable electronic and optical properties, semiconducting polymers have attracted considerable attention in recent years. Among them, organic polymer dots process large breadth of potential synthetic diversity are the representative of photocatalysts for hydrogen production, which presents both an opportunity and a challenge. In this mini-review, first, the organic polymer photocatalysts were introduced. Then, recent reports on polymer dots which showed a superior photocatalytic activity and a robust stability under visible-light irradiation, for hydrogen production were summarized. Finally, challenges and outlook on using organic polymer dots-based photocatalysts from hydrogen production were discussed.

关键词： polymer dots (Pdots) photocatalysis hydrogen production

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含铝温压炸药及其爆炸效能研究

裴明敬,胡华权,张景森,于琴,刘瑜,陈立强

《中国工程科学》 2009年第11卷第4期页码 67-75

摘要：

主要阐述含铝温压炸药配方的基本组成及在不同环境条件下的能量释放效率、爆炸火球及冲击波的形成过程等。通过测试含铝温压炸药在氧气、空气和氩气环境中的燃烧热值，研究不同环境对其爆炸能量释放效率的影响及其使用范围；通过测试爆炸火球和冲击波的成长过程、火球温度和高温火球持续的时间分析含铝温压炸药爆炸机理和破坏效能。结果表明，以超细片状铝粉为主要原料的含铝温压炸药在有氧环境中爆炸的能量释放效率和能量释放速率均较高，其有效破坏效能为较强的爆炸冲击波和持续的高温火球，大大延展温压炸药的综合破坏效能。

关键词：含铝温压炸药爆炸效能冲击波爆炸火球

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Construction of interfacial dynamic bonds for high performance lignin/polymer biocomposites

《化学科学与工程前沿（英文）》 2023年第17卷第10期页码 1372-1388 doi: 10.1007/s11705-023-2302-3

摘要： Lignin is the largest natural aromatic biopolymer, but usually treated as industrial biomass waste. The development of lignin/polymer biocomposites can promote the high value utilization of lignin and the greening of polymers. However, the weak interfacial interaction between industrial lignin and polymer induces poor compatibility and serious agglomeration in polymer owing to the strong intermolecular force of lignin. As such, it is extremely difficult to prepare high performance lignin/polymer biocomposites. Recently, we proposed the strategy of in situ construction of interfacial dynamic bonds in lignin/polymer composites. By taking advantage of the abundant oxygen-containing polar groups of lignin, we inserted dynamic bonding connection such as hydrogen bonds and coordination bonds into the interphase between lignin and the polymer matrix to improve the interfacial interactions. Meanwhile, the natural amphiphilic structure characteristics of lignin were utilized to construct the hierarchical nanophase separation structure in lignin/polymer composites. The persistent problems of poor dispersity and interfacial compatibility of lignin in the polymer matrix were effectively solved. The lignin-modified polymer composites achieved simultaneously enhanced strength and toughness. This concise review systematically summarized the recent research progress of our group toward building high-performance lignin/polymer biocomposites through the design of interfacial dynamic bonds (hydrogen bonds, coordination bonds, and dynamic covalent bonds) between lignin and different polymer systems (polar plastics, rubber, polyurethane, hydrogels, and other polymers). Finally, the future development direction, main challenges, and potential solutions of lignin application in polymers were presented.

关键词： lignin polymer interfacial dynamic bonds